@Idkmaybe,
If the ophthalmologist can guarantee you 40 or more hours, then take that one as it is more money.
Personally, I would go with the museum, as they aren't screwing around with the hours (you may find you get dressed up and they give you 30 minutes' worth of work and then you go home) plus there you would have a set schedule, which I imagine would make things far easier for day care scheduling, etc.