@Sleepy-Eyes,
Do you trust your girlfriend?
If the answer is yes, then who the hell cares what's going on with the guy? If he asks again, she'll refuse. And, most likely, won't get herself back into that sort of a situation with him (which, as you pointed out, was before you were dating - so let it go, ferchrissakes).
If the answer is no, then you've got 99 problems and your friend ain't one of 'em.