@freakingout32,
Make it clear that if she loses her job due to her addiction, you won't be keeping her as a free roommate and she'll have to move out. And mean it.
I don't love ultimatums but sometimes they are necessary. Her nonsense is threatening not just her job (and potentially her health, as video game addicts don't often exercise or eat terribly well), but also your financial independence and probably your credit score, etc. All of which will affect you for a while -- and you're not even the addict.
And tell her, also, that you are willing to help her find a means to break her behaviors. This can mean going to a doctor or the like. You do care for her so I'm sure you would rather not end it. So bring out both the stick and the carrot.
But if she won't at least try to break herself of the addiction (expect setbacks -- they are normal, I understand), then you'll know what's #1 in her life, and it wouldn't be you.
Note: I am not a doctor.