Well, it is known since some time that the old Hittite texts (1650 to 1595 BC), which are preserved in copies from the empire period (c. 1400-c. 1190 BC), are the earliest Indo-European texts that have thus far been found.
Quote:The term Indo-Hittite was proposed by scholars who believed that Hittite and the other closely related Anatolian languages represented a language branch coordinate with all the other Indo-European languages combined, rather than forming another branch coordinate with the individual Indo-European branches (Celtic, Germanic, etc.). In other words, they proposed that at one time there existed a protolanguage (Indo-Hittite) that split into two branches, Anatolian and Indo-European (from which the various branches of Indo-European later evolved). Most scholars, however, consider the Anatolian languages, including Hittite, to be simply a branch of Indo-European.
source: Encyclopædia Britannica. 2004. Encyclopædia Britannica Premium Service.
11 Dec. 2004 <http://www.britannica.com/eb/article?tocId=9042331>