@bluebreezz,
I'm assuming you're the young girl?
Do you have any romantic feelings for this guy? You seem very concerned about what he thinks about you. If you do, and he's married, he may have noticed that and decided to make it abundantly clear that he's not available.
More likely, it's just his personality.
What culture do you hail from? I wonder if it's one where men are typically shown a certain amount of deference?
In general, I actually agree with Fido -- don't worry about it too much, enjoy your friendship with the person your age in this volunteer group, and otherwise just kind of look elsewhere for social interaction.