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biodiesel

 
 
flaja
 
  1  
Reply Fri 28 Dec, 2007 11:16 am
fishin wrote:
Because the majority of places where the fuel is used don't have any local sources for the crops.


Assuming that additional crops are not planted where biodiesel is demanded.

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Apparently not. The difference in mileage between gasoline and normal diesel fuel hasn't prompted many to pay the additional cost for a diesel car as it is.


Because diesel fuel is so much more efficient than gasoline is, diesel cars became rather popular in the 1970s and early 1980s.

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Getting 400 miles from home nad then having to pay to have your vehicle towed back home so you can refill it doesn't appeal to many.


Most people don't work 400 miles from home. Biodiesel would be OK for most people's everyday use. If you need to take a long road trip, rent a car or take a bus.

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There is no doubt that it is possible for "some parts" of the country. I doubt it can be done for large parts of the country though.


In time.

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What effect does the economy of scale have when you have to truck the raw materials to those areas where the crops can't be grown locally vs. trucking the finished product?


Don't we have to truck gasoline long distances because most parts of the country lack crude oil and/or refineries and/or tank farms? What would be the difference between petroleum products and vegetable oil?

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Biodiesel conversion plants (even small ones) are refineries. Each and every one of them would require EPA approval to open and operate just as current diesel refineries require permits.


To my knowledge the EPA does not now regulate biodiesel production and I see no environmental reason why biodiesel production facilities would need EPA regulations. If you have specifics otherwise, give them. Furthermore, the federal government can only regulate interstate/international commerce. You'd be hard-pressed to say producing biodiesel for your own use or for sale strictly within your local community constitutes interstate/international commerce. The EPA likely would not have constitutional jurisdiction.
0 Replies
 
fishin
 
  1  
Reply Fri 28 Dec, 2007 12:11 pm
flaja wrote:
fishin wrote:
There is a table listed here that goes through various crops and lists the typical production on a per acre basis.


Other questions must also be considered:

1. Which of these crops produce oil that is suitable for diesel fuel?


Every one of them in the table.

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2. Which of the crops from #1 are too valuable as food or other-non fuel uses to be used as fuel?


To valuable to whom? That's a relative question.

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3. Of the crops that are suitable as fuel crops which ones have the lowest productions costs in terms of money and thus would make an economically viable fuel source?

4. Of the crops that are suitable as fuel crops which ones have the lowest environmental impacts and thus make an ecologically viable fuel source?

5. Do all of the viable oil crops produce fuels that have the same efficiency?


No idea what the answers are to these at the moment.

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I am fully aware of that. And it isn't an apples/oranges comparison. It is a recognition of the fact that 90% of the vehicles currently on the road burn gasoline.


What has this to do with the relative fuel, economic and environmental values of ethanol and biodiesel?[/quote]

Most people would consider having to replace their vehicle to be a fairly large economic value.

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Those vehicles will never be converted to biodiesel so you will never convince their owners to invest in biofuels if you don't provide some benefit to them directly.


If the economy were to go south, gasoline prices would be incentive enough. Just witness what happened to gas-guzzling cars in the 1970s.

But if 90% of the vehicles on the road now cannot use diesel/biodiesel, what makes you think the big oil companies, that are making huge profits with gas, would ever bother to invest in biofuel technology?


Because there uis a huge commercial market for biodiesel if it can be produced cheaper than conventional diesel and heating fuels.


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Biodiesel doesn't "get" anything. The mpg obtained is by the vehicle. The VW Jetta diesel conversions typically get 50mpg. A Ford F-350 gets 18-20 and a typical tractor trailer truck gets ~3-4 mpg All of them can (and have) run on biodiesel. So MPG is a poor measure of comparison.


No it is not. If biodiesel costs $x a gallon to make and you can get y miles to the gallon while ethanol costs $a a gallon to make and you can get b miles to the gallon, which fuel is more cost effective?


Yes, it is. Each diesel vehicle will get different mileage as will each vehicle running ethanol. Comparing between them becomes an exercise in futility. It is significantly easier to look at the available energy in each fuel and do the calculations from there.

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Both require more energy to produce than they create. The net loss in a corn -> ethanol conversion is ~29%. The net loss in soy -> biodiesel conversion is ~27%.


Are you counting the energy needed to grow the crops or just the energy needed to turn the finished crop into fuel? It know that it takes a good deal of heat to make corn warm enough for it to ferment into alcohol and then to remove the alcohol from the water via distillation. However, according to the episode of Dirty Jobs you only have to heat the biodiesel reagents to 130 degrees Fahrenheit. I would assume that such modest heating could be accomplished with solar energy.


Those numbers came from a Uinv. Of Missouri WWW site that claimed to include the total production cost - growing, converting and transporting.

Converting waste veggie oil to biodiesel may only require 130 degree heat. (many of the kits use home-type hot water heaters so I'd assume that to be true) but that ignores the energy necessary to create the veggie oil to begin with. It also ignores the energy and cost required to generate and transport the methanol and lye that have to be added to the veggie oil to do the conversion. Solar heat might be an option for the final phase of the process - I don't know.
0 Replies
 
fishin
 
  1  
Reply Fri 28 Dec, 2007 12:39 pm
flaja wrote:
fishin wrote:
Because the majority of places where the fuel is used don't have any local sources for the crops.


Assuming that additional crops are not planted where biodiesel is demanded.


And assuming there is space to plant those crops. I did a quick calculation based on my own usage from when I lived in Maine. If my own own usage is typical for a household across the state and if soy were used to create biodiesel the entire landmass of the state of Maine would have to be plowed over and planted with soy to produce enough biodiesel to satisfy the demand for residental/personal use in the state (based on it's 2000 population.) It just happens to work out that the balance is almost perfect for that particuar state. Every single square mile of the state would have to be planted with soy just to satisfy it's own demand.

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Apparently not. The difference in mileage between gasoline and normal diesel fuel hasn't prompted many to pay the additional cost for a diesel car as it is.


Because diesel fuel is so much more efficient than gasoline is, diesel cars became rather popular in the 1970s and early 1980s.


"Popular" is a relative term. I doubt the percentage of diesels has ever exceeded 10% of the passenger vehicle market.

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Getting 400 miles from home and then having to pay to have your vehicle towed back home so you can refill it doesn't appeal to many.


Most people don't work 400 miles from home. Biodiesel would be OK for most people's everyday use. If you need to take a long road trip, rent a car or take a bus.


*nods* Sure. I'll bet a lot of people are going to pack up the family and take a bus to go on vacation.

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There is no doubt that it is possible for "some parts" of the country. I doubt it can be done for large parts of the country though.


In time.


Only if you wipe out half the population. We aren't going to gain much landmass anywhere to grow more crops on.

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What effect does the economy of scale have when you have to truck the raw materials to those areas where the crops can't be grown locally vs. trucking the finished product?


Don't we have to truck gasoline long distances because most parts of the country lack crude oil and/or refineries and/or tank farms? What would be the difference between petroleum products and vegetable oil?


There wouldn't be much difference at all. But that sort of defeats you "local" argument doesn't it? The current cost is based on those large corporations that you hate so much doing the transporting.

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Biodiesel conversion plants (even small ones) are refineries. Each and every one of them would require EPA approval to open and operate just as current diesel refineries require permits.


To my knowledge the EPA does not now regulate biodiesel production and I see no environmental reason why biodiesel production facilities would need EPA regulations. If you have specifics otherwise, give them. Furthermore, the federal government can only regulate interstate/international commerce. You'd be hard-pressed to say producing biodiesel for your own use or for sale strictly within your local community constitutes interstate/international commerce. The EPA likely would not have constitutional jurisdiction.


Well... your knowledge is wrong. "Section 211 of the Clean Air Act provides EPA with the authority to regulate fuels and fuel additives in order to obtain information about emissions and health effects related to fuels and their additives, and where appropriate to reduce the risk to public health from exposure to their emissions."

http://www.epa.gov/otaq/renewablefuels/420b07019.pdf

Producing biodiesel for personal comsumption may not constitute interstate commerce - unless of course you travel across state lines in your vehicle and do something silly like... buy something.

The moment it starts being sold publicly however, you've opened it up to being used by commercial vehicles. Who's going to ensure those vehicles stay within the state's boundaries? Of course the EPA is also responsible for things like water pollution so if you can demonstrate that your production site is 100% isolated from any ground water aquifer that either crosses state lines or runs into a waterway that crosses state lines or dumps into an ocean you just might be able to limit their control.

And then there are the state level environmental agencies that are also going to jump into the regulatory game and they don't have to worry about the Federal Constitution. They aren't going to be real happy about some mom and pop shop having occassional leaks of toxic fuels into public watersheds either.
0 Replies
 
maporsche
 
  1  
Reply Fri 28 Dec, 2007 01:03 pm
Forget about bio-fuels....electricity is where the future lies.

Bio-fuels will never become mass market, there is no infrastructure for them.

Electricity on the other hand is everywhere.
0 Replies
 
flaja
 
  1  
Reply Fri 28 Dec, 2007 01:58 pm
fishin wrote:
To valuable to whom? That's a relative question.


Value in simple dollar amounts. If the price for a gallon of biodiesel is $x and the price for enough cashew nuts to produce a gallon of biodiesel is $x + 1, it would be foolish to turn cashews into biodiesel.

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Most people would consider having to replace their vehicle to be a fairly large economic value.


Such a large scale replacement of vehicles wouldn't be outside of this country's living experience. When the OPEC oil embargo hit in the early 1970s my mother as a bookkeeper for a Pontiac dealership. The people that worked at the dealership had a running pool betting on how many Cadilacs they would find the next morning parked on the lot with the keys locked inside. If the cars were placed end-to-end they would have reached from the dealership to the GMAC office a few blocks away. It is entirely conceivable that the cost of gasoline-based fuels can increase so much that most Americans would make wholesale changes in their lifestyles.

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Because there uis a huge commercial market for biodiesel if it can be produced cheaper than conventional diesel and heating fuels.


Apparently biodiesel can be produced at a lower cost than gasoline or #2 fuel oil can be. But as long as people are dependent on gasoline and #2 fuel oil and oil companies can make high profits as a consequence of that dependence, they aren't going to do any R%D for non-petroleum alternatives. As long as people can make biodiesel in their garage, the potential for gutting oil company profits is in place. Oil companies are not going to enter a market where every consumer is a potential competitor. As long as you can make biodiesel yourself, you won't be dependent on the oil companies. Thus the oil companies aren't likely to try to compete with you.

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Yes, it is. Each diesel vehicle will get different mileage as will each vehicle running ethanol.


Thus you would use a standard model vehicle for comparison purposes.

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Those numbers came from a Uinv. Of Missouri WWW site that claimed to include the total production cost - growing, converting and transporting.


Can you provide a link to this study?

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Converting waste veggie oil to biodiesel may only require 130 degree heat. (many of the kits use home-type hot water heaters so I'd assume that to be true) but that ignores the energy necessary to create the veggie oil to begin with.


Which would likely be more for corn-based ethanol than it would be for soy-based biodiesel since you need more fertilizer for corn than you do for soy. Also soy can be grown in places where corn cannot be. Corn is more suitable for Iowa than Georgia, while soy is more suitable for Georgia than corn is.

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It also ignores the energy and cost required to generate and transport the methanol and lye that have to be added to the veggie oil to do the conversion.


As opposed to the energy needed to transport the yeast and sugar(?) needed to turn corn into ethanol?
0 Replies
 
Walter Hinteler
 
  1  
Reply Fri 28 Dec, 2007 02:27 pm
flaja wrote:
My understanding is that Rudolf Diesel ran his engine on peanut oil. His goal was to build an engine that farmers could fuel themselves with the crops they could grow.


Well, I wouldn't translate "Petroleum" as peanut oil. But certainly you might know it better.
0 Replies
 
flaja
 
  1  
Reply Fri 28 Dec, 2007 02:37 pm
fishin wrote:
And assuming there is space to plant those crops.


Farmland that is currently in land banks, where the farmer collects a government check for growing nothing in order to save the soil, could be brought into production. Since soybeans (and peanuts) produce their own nitrogen fertilizer, growing them is actually good for the soil.

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I did a quick calculation based on my own usage from when I lived in Maine.


I am not aware that you can grow soybeans in Maine, so what are you basing your production data on? I would assume that your chart from http://journeytoforever.org/biodiesel_yield.html is based on idealized growing conditions. The source itself says that crop yields can vary widely. If you want to rely on localized production farmers would naturally concentrate on the crops that are most suitable for their local climate and soil conditions.

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"Popular" is a relative term. I doubt the percentage of diesels has ever exceeded 10% of the passenger vehicle market.


There was a time when diesel engines were confined to commercial trucks and other very large vehicles. But during the 1970s automakers started putting diesel engines in cars and pick-up trucks because such vehicles were in demand because of their fuel efficiency.

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*nods* Sure. I'll bet a lot of people are going to pack up the family and take a bus to go on vacation.


Ever heard of Greyhound? You cannot judge the demand for a certain type of vehicle based solely on vacation travel. A family's daily commute is far more important.

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Only if you wipe out half the population. We aren't going to gain much landmass anywhere to grow more crops on.


And we likely do not fully utilize all of the farmland that we do have let alone the empty land that is not located on farms. At 48 gallons of diesel fuel to the acre for soybeans and 40 miles to the gallon I could grow enough soy on my ¾ acre urban lot to drive 1440 miles a year (or 3300 miles a year if I grew peanuts). My neighbor's lot is about a half acre and I have 2 empty lots on the other side of me that likely have 1.5 to 2 acres between them. Put all of this space together and you can drive for 5000 miles on the soy that could be grown. This would be maybe 5 months worth of local driving.

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There wouldn't be much difference at all.


Then what are you complaining about?

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But that sort of defeats you "local" argument doesn't it? The current cost is based on those large corporations that you hate so much doing the transporting.


But would biodiesel need so much transporting? If you grow the crops locally, press the oil locally and convert it to biodiesel locally, you don't need much transportation.

Within 200 miles of where I live in Florida you could theoretically grow for commercial consumption:

calendula
cotton
mustard seed
peanuts
pecan nuts
pumpkin seed
soybean

Some of these crops are already grown commercially in my area. Others are common flower/vegetable garden crops. But these crops are not grown here for fuel purposes because there isn't yet enough fuel demand.

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Well... your knowledge is wrong. "Section 211 of the Clean Air Act provides EPA with the authority to regulate fuels and fuel additives in order to obtain information about emissions and health effects related to fuels and their additives, and where appropriate to reduce the risk to public health from exposure to their emissions."


Unless harmless biodiesel exhaust is actually air pollution (which can travel to other states) a purely localized biodiesel production could not be regulated by the federal government because the federal government doesn't have jurisdiction over a state's internal commerce.

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The moment it starts being sold publicly however, you've opened it up to being used by commercial vehicles.


Neither a diyer, nor a non-profit co-op, would likely sell biodiesel to the general public.

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And then there are the state level environmental agencies that are also going to jump into the regulatory game and they don't have to worry about the Federal Constitution.


They've got to worry about voters who want cheap fuel, however.
0 Replies
 
fishin
 
  1  
Reply Fri 28 Dec, 2007 03:33 pm
flaja wrote:


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Most people would consider having to replace their vehicle to be a fairly large economic value.


Such a large scale replacement of vehicles wouldn't be outside of this country's living experience. When the OPEC oil embargo hit in the early 1970s my mother as a bookkeeper for a Pontiac dealership. The people that worked at the dealership had a running pool betting on how many Cadilacs they would find the next morning parked on the lot with the keys locked inside. If the cars were placed end-to-end they would have reached from the dealership to the GMAC office a few blocks away. It is entirely conceivable that the cost of gasoline-based fuels can increase so much that most Americans would make wholesale changes in their lifestyles.


That's funny. I happen to have been working in a gas station during the OPEC oil embargo and pretty clearly recall filling those cars with gas every day. But the OPEC oil embargo issues had little to do with the cost of gas so it's hardly an apt example. The national average retail price of a gallon of gas only rose by $.17 during the embargo. The fact that gas stations couldn't get gas at any price was what set people off.


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Because there uis a huge commercial market for biodiesel if it can be produced cheaper than conventional diesel and heating fuels.


Apparently biodiesel can be produced at a lower cost than gasoline or #2 fuel oil can be. But as long as people are dependent on gasoline and #2 fuel oil and oil companies can make high profits as a consequence of that dependence, they aren't going to do any R%D for non-petroleum alternatives. As long as people can make biodiesel in their garage, the potential for gutting oil company profits is in place. Oil companies are not going to enter a market where every consumer is a potential competitor. As long as you can make biodiesel yourself, you won't be dependent on the oil companies. Thus the oil companies aren't likely to try to compete with you.

Again, the only way you can say that biodiesel is cheaper to produce is to assume that everyone would have access to waste oil at little or no cost.

The current cost to produce a gallon of gasoline is about $2.50/gallon. The cost for raw soybean oil is currently $2.54/gallon and that would still need to be converted to biodiesel further increasing it's cost.

Garage operations aren't going to cut into any oil company's profits. That's purely delusional.

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Yes, it is. Each diesel vehicle will get different mileage as will each vehicle running ethanol.


Thus you would use a standard model vehicle for comparison purposes.


That works fine if you are buying that specific model. But nothing determined there would apply to any other model though so why bother?

We already know that each gallon #2 diesel fuel contains 130,000 BTUs of energy. A gallon of biodiesel (B100) contains 120,000 BTUs, a gallon of gasoline contains 115,000 BTUs, a gallon of Ethanol (E85) contains 80,000 BTUs. Finding a standard model and recalculating for variances between them isn't necessary. We have established constants. #2 Diesel will always contain more energy per gallon than biodiesel, biodiesel will always contain more energy per gallon than gasoline, etc...

Only two calculations ever need to be done using these constants to make any comparison - the cost to produce per BTU and the efficency of use for each BTU. And that applies to cars, trucks, furnaces, electrical generators, etc... There is no need for additional calculations for weight and design differences.

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Those numbers came from a Uinv. Of Missouri WWW site that claimed to include the total production cost - growing, converting and transporting.


Can you provide a link to this study?


I'll have to find it again. I've moved over to the g/f's house in between postings here.

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It also ignores the energy and cost required to generate and transport the methanol and lye that have to be added to the veggie oil to do the conversion.


As opposed to the energy needed to transport the yeast and sugar(?) needed to turn corn into ethanol?


There is no need to transport yeast after the first load. Yeast grows on it's own right there at the refinery. And there is no need for sugar. Refining ethanol is the process of extracting the natural sugars from the base crop (i.e. corn). That's why corn works for producing ethanol and things like tree bark don't (at least not very well). Corn has a high sugar content. Sugar beets or sugar cane have an even higher natural sugar content which is why they are even better alternatives than corn.
0 Replies
 
fishin
 
  1  
Reply Fri 28 Dec, 2007 04:09 pm
flaja wrote:
fishin wrote:
And assuming there is space to plant those crops.


Farmland that is currently in land banks, where the farmer collects a government check for growing nothing in order to save the soil, could be brought into production. Since soybeans (and peanuts) produce their own nitrogen fertilizer, growing them is actually good for the soil.


There isn't enough of it. You can slice it and dice it any way you'd like but there isn't enough landmass.

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I did a quick calculation based on my own usage from when I lived in Maine.


I am not aware that you can grow soybeans in Maine, so what are you basing your production data on? I would assume that your chart from http://journeytoforever.org/biodiesel_yield.html is based on idealized growing conditions. The source itself says that crop yields can vary widely. If you want to rely on localized production farmers would naturally concentrate on the crops that are most suitable for their local climate and soil conditions.


I did use the numbers from that chart knowing full well that Maine isn't the ideal location for growng soy (They do grow some). But the fact that it isn't an ideal location just makes the calculations even worse. If they couldn't produce enough at 100% of the amnount listed in the chart how are they going to generate enough at 50%?

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*nods* Sure. I'll bet a lot of people are going to pack up the family and take a bus to go on vacation.


Ever heard of Greyhound? You cannot judge the demand for a certain type of vehicle based solely on vacation travel. A family's daily commute is far more important.


Oh, I've heard of 'em! That's what makes the idea even more laughable.

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Only if you wipe out half the population. We aren't going to gain much landmass anywhere to grow more crops on.


And we likely do not fully utilize all of the farmland that we do have let alone the empty land that is not located on farms. At 48 gallons of diesel fuel to the acre for soybeans and 40 miles to the gallon I could grow enough soy on my ¾ acre urban lot to drive 1440 miles a year (or 3300 miles a year if I grew peanuts). My neighbor's lot is about a half acre and I have 2 empty lots on the other side of me that likely have 1.5 to 2 acres between them. Put all of this space together and you can drive for 5000 miles on the soy that could be grown. This would be maybe 5 months worth of local driving.


Yeah? And where are you going to live when you knock your house down on that 3/4 acre urban lot so you can grow all those soybeans? Don't you think your neighbor might object to you knocking down his house too? What if he wants to knock down his house and grow his own soybeans? I guess you figure he/she doesn't want to be able to drive either?

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There wouldn't be much difference at all.


Then what are you complaining about?


Who's complaining? I'm just pointing out the flaws in your logic.

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But that sort of defeats you "local" argument doesn't it? The current cost is based on those large corporations that you hate so much doing the transporting.


But would biodiesel need so much transporting? If you grow the crops locally, press the oil locally and convert it to biodiesel locally, you don't need much transportation.

Within 200 miles of where I live in Florida you could theoretically grow for commercial consumption:

calendula
cotton
mustard seed
peanuts
pecan nuts
pumpkin seed
soybean

Some of these crops are already grown commercially in my area. Others are common flower/vegetable garden crops. But these crops are not grown here for fuel purposes because there isn't yet enough fuel demand.

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Well... your knowledge is wrong. "Section 211 of the Clean Air Act provides EPA with the authority to regulate fuels and fuel additives in order to obtain information about emissions and health effects related to fuels and their additives, and where appropriate to reduce the risk to public health from exposure to their emissions."


Unless harmless biodiesel exhaust is actually air pollution (which can travel to other states) a purely localized biodiesel production could not be regulated by the federal government because the federal government doesn't have jurisdiction over a state's internal commerce.


Biodiesel exhaust isn't harmless and thusfar every branch of the Federal government as well as every state government disagrees with your legal assesment.

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And then there are the state level environmental agencies that are also going to jump into the regulatory game and they don't have to worry about the Federal Constitution.


They've got to worry about voters who want cheap fuel, however.


And voters who want clean air and water... So far they seem to be the one's winning out in WI, WA, CA, AL, NH, MA, CT, RI, etc...
0 Replies
 
fishin
 
  1  
Reply Fri 28 Dec, 2007 04:54 pm
Re: biodiesel
I just ran into something that sort of addresses your original question here.

flaja wrote:

Does anyone know how much farmland would be needed to grow enough oil crops to meet the nation's auto fuel demands if vegetable oil (straight from the farm; not recycled from kitchens) were the only auto fuel we used?



http://www.unh.edu/p2/biodiesel/article_alge.html

In that he addresses generating biodiesel from algae (which seems to be a popular idea for those researching alternative fuels) and comes up with a figure of 15,000 square miles of farmland (algaeland?) to replace all current vehicle fuels with biodiesel from algae.

If we use his same 140.8 billion gallon number and use the other chart I previously linked we'd need 347,000 sq. miles of palms, 1.95 million sq miles for peanuts, 4.58 million sq. miles for soybeans or 12.2 million sq. miles of corn.

The total U.S landmass is ~3.7 million sq. miles.

Interesting numbers...
0 Replies
 
flaja
 
  1  
Reply Fri 28 Dec, 2007 04:58 pm
fishin wrote:
That's funny. I happen to have been working in a gas station during the OPEC oil embargo and pretty clearly recall filling those cars with gas every day.


Didn't most gas stations at the time sell both gasoline and diesel?

Doesn't a small, compact gasoline-powered car that has high fuel efficiency still require gas? You may not have had any shortage of customers, but you likely saw your customers reduce the amount of gas they bought.

Whether or not people bought gas does not affect whether or not they gave up large gas-guzzling cars for small, more fuel-efficient cars or cars powered with diesel. Just because gas remained on the market doesn't mean that people didn't make wholesale changes in their lifestyles.

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But the OPEC oil embargo issues had little to do with the cost of gas so it's hardly an apt example.


You are either in la-la land or you are a fool. I'm sorry I wasted so much time discussing this issue with you. You obviously don't have a clue about the real world.
0 Replies
 
Clary
 
  1  
Reply Sat 12 Jan, 2008 04:45 am
www.theaircar.com is the future!!!!
0 Replies
 
Solve et Coagula
 
  1  
Reply Sat 12 Jan, 2008 05:39 am
Scientists Use Sunlight to Make Fuel From CO2
Scientists Use Sunlight to Make Fuel From CO2

By Chuck Squatriglia 01.04.08, 8:00 PM

Sandia researcher Rich Diver checks out the solar furnace which will be the
initial source of concentrated solar heat for converting carbon dioxide to
fuel. Eventually parabolic dishes will provide the thermal energy.

Researchers at Sandia National Laboratories in New Mexico have found a way
of using sunlight to recycle carbon dioxide and produce fuels like methanol
or gasoline.

The Sunlight to Petrol, or S2P, project essentially reverses the combustion
process, recovering the building blocks of hydrocarbons. They can then be
used to synthesize liquid fuels like methanol or gasoline. Researchers said
the technology already works and could help reduce greenhouse-gas emissions,
although large-scale implementation could be a decade or more away.
"This is about closing the cycle," said Ellen Stechel, manager of Sandia's
Fuels and Energy Transitions department. "Right now our fossil fuels are
emitting CO2. This would help us manage and reduce our emissions and put us
on the path to a carbon-neutral energy system."

The idea of recycling carbon dioxide is not new, but has generally been
considered too difficult and expensive to be worth the effort. But with oil
prices exceeding $100 per barrel and concerns about global warming mounting,
researchers are increasingly motivated to investigate carbon recycling. Los
Alamos Renewable Energy, for example, has developed a method of using CO2 to
generate electricity and fuel.

S2P uses a solar reactor called the Counter-Rotating Ring Receiver Reactor
Recuperator, or CR5, to divide carbon dioxide into carbon monoxide and
oxygen.

"It's a heat engine," Stechel said. "But instead of doing mechanical work,
it does chemical work."

Lab experiments have shown that the process works, Stechel said. The
researchers hope to finish a prototype by April.

The prototype will be about the size and shape of a beer keg. It will
contain 14 cobalt ferrite rings, each about one foot in diameter and turning
at one revolution per minute. An 88-square meter solar furnace will blast
sunlight into the unit, heating the rings to about 2,600 degrees Fahrenheit.
At that temperature, cobalt ferrite releases oxygen. When the rings cool to
about 2,000 degrees, they're exposed to CO2.

Since the cobalt ferrite is now missing oxygen, it snatches some from the
CO2, leaving behind just carbon monoxide -- a building block for making
hydrocarbons -- that can then be used to make methanol or gasoline. And with
the cobalt ferrite restored to its original state, the device is ready for
another cycle.

Fuels like methanol and gasoline are combinations of hydrogen and carbon
that are relatively easy to synthesize, Stechel said. Methanol is the
easiest, and that's where they will start, but gasoline could also be made.
However, creating a powerful and efficient solar power system to get the
cobalt ferrite hot enough remains a major hurdle in implementing the
technology on a large scale, said Aldo Steinfeld, head of the Solar
Technology Laboratory at the Paul Scherrer Institut in Switzerland, in an
e-mail.

He and Stechel said the technology could be 15 to 20 years from viability on
an industrial scale.

The Sandia team originally developed the CR5 to generate hydrogen for use in
fuel cells. If the device's rings are exposed to steam instead of carbon
dioxide, they generate hydrogen. But the scientists switched to carbon
monoxide, so the fuels they produce would be compatible with existing
infrastructure.

Stechel said the Sandia team envisions a day when coal-fired power plants
might have large numbers of CR5s, each reclaiming 45 pounds of carbon
dioxide using reclamation technology currently under development and
producing enough carbon monoxide to make 2.5 gallons of fuel. The Sunlight
to Petrol process also raises the possibility that liquid hydrocarbon fuels
might one day be renewable - provided CO2 reclamation reaches a point where
the greenhouse gas can be snatched directly from the air. Such a process is
being explored by Global Research Technologies and Klaus Lakner of Columbia
University, among others.

http://www.wired.com/science/discoveries/news/2008/01/S2P
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