ican711nm wrote:parados wrote:
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If you are correct Ican, it would mean much of what we know about the universe could well be wrong since spectroscopy requires that molecules always react the same to electromagnetic energy.
More correctly stated: spectroscopy requires that molecules OF THE SAME KIND WITHIN THE SAME PHYSICAL CONDITIONS always react the same to electromagnetic energy.
I see. So then you will provide us of the source for your claim that CO2 doesn't absorb as much IR when it is in water vapor?
http://www.psinvention.com/mixtures.htm
Brief Outline Of Molecular Mixtures
There are basically 3 types of mixtures. They can be characterized by how they combine ( interaction with the solute (substance being disolved) and solvent ( dissolving medium)) as well as how they can be separated.
Suspension:
The ingredients are (stirred) in. If left alone, they will settle out. The heavier ingredient will settle to the bottom. Filtration can seperate the two ingredients. An example would be dirt mixed with water.
Colloidial:
The size of the solute is smaller than in a suspension, but greater than in a solution (see below). The solute breaks down but remains as a clump of molecules and is smaller than the eye can see. Colloids are a bit unusual in that the solute is equally dispersed in the solvent as in a solution, but the solute does not completely break down. In many cases this is because something coats the bits of solute and prevents them from completely disolving in the solvent. An example would be mayonaise, jello or Oobleck.
Solution:
The solute and solvent are dissolved and cannot be separated unless one of the ingredients changes state of matter. ie. distilation, (evaporating) or crystallation. An example would be salt and water.
Home Page of Poseidon Software and Invention.
http://www.grc.nasa.gov/WWW/RT2002/5000/5480jaworske.html
Solar Selective Coatings Prepared From Thin-Film Molecular Mixtures and Evaluated
Thin films composed of molecular mixtures of metal and dielectric are being considered for use as solar selective coatings for a variety of space power applications. By controlling molecular mixing during ion-beam sputter deposition, researchers can tailor the solar selective coatings to have the combined properties of high solar absorptance and low infrared emittance. On orbit, these combined properties simultaneously maximize the amount of solar energy captured by the coating and minimize the amount of thermal energy radiated. The solar selective coatings are envisioned for use on minisatellites, for applications where solar energy is used to power heat engines or to heat remote regions in the interior of the spacecraft. Such systems may be useful for various missions, particularly those to middle Earth orbit.
http://www.udel.edu/Geography/DeLiberty/Geog474/geog474_energy_interact.html
Geog 474
Energy Interactions with the Atmosphere and at the Surface
Solar and Terrestrial Radiation
Most remote sensing instruments are designed to detect solar radiation and terrestrial radiation
Solar radiation
emr emitted from sun which passes through the atmosphere and is reflected in varying degrees by Earth's surface and atmosphere
detectable only during daylight
A nice load of crap that doesn't explain anything about which spectrum CO2 absorbs when it is suspended in water compared to when it is not suspended.
By mixing molecules scientists can use different molecules to absorb specific wavelengths. Since one molecule doesn't absorb all the wavelengths they just selectively pick the molecules to absorb the required wavelengths. Water vapor doesn't absorb all the wavelengths that CO2 does. You have shown me nothing that even comes close to answering my question. Mixing molecules doesn't make the individual molecules absorb different wavelengths.
I will ask again. What source do you have that shows that a CO2 atom suspended in water does not absorb any energy in the infrared range. Every paper I have looked at shows that CO2 does absorb IR when suspended in water which is why they can use spectography to tell that the water contains CO2
OK! So now all we have to focus our attention on, is the source of that infrared radiation and the cause of its variable intensity over past millennia as well as past centuries and decades. Some say the most immediate source is the CO2 in the atmosphere. But much of that CO2 in the atmosphere is mixed with H2O. Consequently, its ability to radiate infrared light from the infrared radiation it receives from earth is somewhat reduced. So as the global temperature rises, more H2O would evaporate into the atmosphere and reduce further the atmospheric CO2's ability to radiate infrared. That would then lead to global cooling.
the infrared radiation it receives from earth is somewhat reduced. So as the global temperature rises, more H2O would evaporate into the atmosphere and reduce further the atmospheric CO2's ability to radiate infrared. That would then lead to global cooling.
The water vapor continuum is included in a manner consistent with the water vapor line absorption. Fluxes calculated with the model agree with LBLRTM to about 1 W m(-2) for the entire vertical range of the atmosphere for several test cases. The heating rate errors are reduced by as much as 0.25 degrees C day(-1) below the tropopause
Quote:the infrared radiation it receives from earth is somewhat reduced. So as the global temperature rises, more H2O would evaporate into the atmosphere and reduce further the atmospheric CO2's ability to radiate infrared. That would then lead to global cooling.
You claimed that it would lead to cooling..
The science clearly shows it won't. When 2 gases with different spectral radiations are combined you can add the 2 together to get the spectral outcome. When they are not completely different then you have to use a different formula. The formula can be found here.
p.454 - formula for overlapping spectrum
This reference of yours says gas mixtures that contain spectral bands that overlap, will absorb less heat than the sum of the heats each unmixed gas will absorb separately.
If such a mixture of gases absorbs less heat, then that mixture will radiate less heat than their component gases acting alone will radiate.
The individual absorbtion spectrum for water and CO2 can be found here
http://jcbmac.chem.brown.edu/baird/CHEM-F1/Chem-IRC/images/water_CO2Absn.html
You will note that CO2 has an absorbtion band in the 12-18 range that water doesn't completely absorb.
But CO2 does have absorbtion bands in the range of some of the same bands in water. Thus there is some overlap of absorbtion bands in CO2 and water. Therefore a mixture of CO2 and water will absorb less heat than will the sum of both when they are not mixed.
My initial response to your statement about how it would lead to cooling can be found here..
http://www.able2know.org/forums/viewtopic.php?p=2929149#2929149
parados wrote:What? How does H20 affect the absorbtion and radiation rate of CO2? The only thing H20 could do is be so prevalent that it absorbs all the IR so that there is none left for the CO2 to absorb. Of course the H20 would radiate it's own IR at a reduced rate from what it received which again would be radiated in all directions including back toward the earth. ANY green house gas that prevents radiation of the earth's IR to space would lead to warming not cooling.
Some of the studies concerning gas overlap can be found here..
http://www.cgd.ucar.edu/cms/aconley/requirements/refs/corrk_bib.htm
This one shows that water vapor increases the temperature in the atmosphere.
http://www.cgd.ucar.edu/cms/aconley/requirements/refs/each/137.html
Quote:The water vapor continuum is included in a manner consistent with the water vapor line absorption. Fluxes calculated with the model agree with LBLRTM to about 1 W m(-2) for the entire vertical range of the atmosphere for several test cases. The heating rate errors are reduced by as much as 0.25 degrees C day(-1) below the tropopause
I see. So you can't provide any evidence of your claim then. Thanks for clarifying for all of us.
parados wrote:Some of the studies concerning gas overlap can be found here..
http://www.cgd.ucar.edu/cms/aconley/requirements/refs/corrk_bib.htm
This one shows that water vapor increases the temperature in the atmosphere.
http://www.cgd.ucar.edu/cms/aconley/requirements/refs/each/137.html
Quote:The water vapor continuum is included in a manner consistent with the water vapor line absorption. Fluxes calculated with the model agree with LBLRTM to about 1 W m(-2) for the entire vertical range of the atmosphere for several test cases. The heating rate errors are reduced by as much as 0.25 degrees C day(-1) below the tropopause
I agree that the more water vapor in the atmosphere, the more the average temperature of the atmosphere will be. But when that water paper cools, say at night or when blown toward the poles, the more of that water vapor will precipitate out of the atmosphere. The more precipitation of that water vapor the cooler will be the atmosphere.
Thank you, parados, for objectively supplying the evidence you needed to prove me correct.
Clearly, parados, the water vapor in a mixture of water and CO2, doesn't have to absorb all the heat from the sun in a mixture of CO2 and water vapor, in order to reduce the amount of heat absorbed by that mixture.
The water vapor in that mixture only has to absorb some of the heat that unmixed CO2 would absorb, in order to reduce the sum of the absorbtion of heat by that mixture.
Consequently, the greater the ratio of water vapor to CO2 in the atmosphere, the less absorbtion of heat by CO2 there will be in that atmosphere. The warmer the atmosphere gets, the more water vapor evaporated from surface waters there will be in the atmosphere, and the less warming there will be by the CO2 in the atmosphere. Then when the heat absorbtion by CO2 is reduced, the more precipitation of the water-CO2 mixture there will be.
So the amount of CO2 in the atmosphere at any time is less a contributor to atmospheric IR re-radiation, the more H2O there is in the atmosphere. The more H2O there is in the atmosphere, the more CO2 will be precipitated out of the atmosphere.
ican711nm wrote:parados wrote:Some of the studies concerning gas overlap can be found here..
http://www.cgd.ucar.edu/cms/aconley/requirements/refs/corrk_bib.htm
This one shows that water vapor increases the temperature in the atmosphere.
http://www.cgd.ucar.edu/cms/aconley/requirements/refs/each/137.html
Quote:The water vapor continuum is included in a manner consistent with the water vapor line absorption. Fluxes calculated with the model agree with LBLRTM to about 1 W m(-2) for the entire vertical range of the atmosphere for several test cases. The heating rate errors are reduced by as much as 0.25 degrees C day(-1) below the tropopause
I agree that the more water vapor in the atmosphere, the more the average temperature of the atmosphere will be. But when that water paper cools, say at night or when blown toward the poles, the more of that water vapor will precipitate out of the atmosphere. The more precipitation of that water vapor the cooler will be the atmosphere.
Wow... And you think that this would cause global cooling?
I guess we can all agree that your "science" violates the laws of thermodynamics.
parados wrote:
Wow... And you think that this would cause global cooling?
I guess we can all agree that your "science" violates the laws of thermodynamics.
Heat Absorbtion:
W = heat absorbtion for a given amount of water vapor.
C = heat absorbtion for a given amount of carbon dioxide.
A = water vapor spectral bands not included in CO2 spectral bands.
B = carbon dioxide spectral bands not included in H2O spectral bands.
M = spectral bands that are in both H2O vapor and CO2 gas.
Unmixed Water Vapor heat absorbtion, W = A + M
Unmixed Carbon Dioxide heat absorbtion, C = B + M
Total Heat absorbtion of unmixed water vapor and unmixed carbon dioxide = Hm = W + C = A + M + B + M = A + B + 2M.
Total Heat absorbtion of mixed water vapor and mixed carbon dioxide = Hum= W + C = A + M + B + M = A + B + M.
Difference in absorbtion between unmixed and mixed water vapor and carbon dioxide = D(m-um) = Hm - Hum = A + B + 2M - (A + B + M) = M
Therefore, in mixed solutions of water vapor and carbon dioxide, as the amount of water vapor in the atmosphere increases, the amount of heat absorbtion by the M spectral parts of more carbon dioxide molecules will decrease, and that will reduce the total amount of heat absorbed by the CO2 in the atmosphere.
At a higher average earth temperatures, the amount of water vapor in the atmosphere increases. As it increases, the amount of precipitation of mixed water vapor and carbon dioxide will increase at night and nearer the poles, causing the amount of carbon dioxide in the atmosphere to decrease.
The net effect of that will lead to a decrease in the CO2 heating of both the atmosphere and the earth. I perceive such decrease in CO2 heating to be equivalent to cooling.
Now you argue that with an increase in average surface temperature due to increased CO2 in the atmosphere, there will be less precipitation,
not more, despite the increase of water vapor in the atmosphere. What you overlook is the fact that the earth does not warm uniformly. Not only is that cooling and heating variable over the surface of the globe, it is variable by time of day, and seasons of the year. Infact, we note that ice nearer the south pole area is increasing now, while ice nearer the north pole area is decreasing now. That increase in ice nearer the south pole comes from increased precipitation. That decrease in ice nearer the north pole comes from increased temperatures of north polar ocean currents. While the earth's average temperature is alleged to be increasing due to the CO2 in the atmosphere, the south pole area is cooling even while the north pole area is warming.
Now you argue that with an increase in average surface temperature due to increased CO2 in the atmosphere, there will be less precipitation
I never said there would be less precipitation.
ican711nm wrote:Now you argue that with an increase in average surface temperature due to increased CO2 in the atmosphere, there will be less precipitation
parados wrote:I never said there would be less precipitation.
Parados, then what did you say about that?
Your analysis of my equations does not logically relate to what those equations illustrate.
My equations were directed at illustrating that the heat absorbtion of specific amounts of H2O and CO2 is different depending on whether these molecules are mixed or unmixed.
Under specific conditions, the total heat absorbtion of unmixed specific molecule quantities is greater than the total heat absorbtion of mixed same specific quantities. The magnitude of that difference is related to the amount of common spectral bands of H2O and CO2, as well as the specific quantities of H2O and CO2 molecules being measured.
Do you agree or disagree?
Currently, the global temperature increase over the last 100 years is estimated by many weather scientists to be 0.5C. But double that, if you believe that, and we still know that mixing one arbitrary amount of CO2 with another arbitrary amount of H2O reduces the heat absorbtion of that mixture to less than what the sum of the heat absorbtions of each of those amounts when not mixed with the other.
Do you agree or disagree?
Increasing the amount of water vapor in the atmosphere will increase the amount of precipitation of mixtures of H2O and CO2 from the atmosphere, thereby decreasing the amount the earth's temperature would otherwise rise.
Do you agree or disagree?
Almost all the earth's rain forests and jungles-are in the tropical zone! Even though its much warmer in the tropical zone, precipitation in parts of that zone are nonetheless great enough to promote rain forests!
Do you agree or disagree?
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If rain takes so much CO2 out of the atmosphere then as we have increased the amount of CO2 in the atmosphere would there not be more taken out in present rains?
Yes! And even more in subsequent rains.
Wouldn't this mean that we would NOT have an increase in atmospheric CO2?
No! It would mean we would have less CO2 in the atmosphere than we otherwise would if it didn't rain.
CONCLUSION
We do not really know whether there has been discovered a scientific cause-and-effect correlation between the amount of CO2 in the atmosphere over the last 100 years and the alleged global warming over the same time period. In fact the increases or decreases in global temperature may have far more to do with amount of H2O evaporated into the atmosphere from surface water because of variations in the intensity of the sun's radiation than they have to do with the amount of CO2 in the atmosphere. Also, we know that the amount of heat absorbtion by the CO2-H2O-mixture in the atmosphere is smaller than if there were no CO2 in the atmospheric H2O. Consequently, the CO2 does not enhance the net heat absorbtion by the atmosphere. It reduces it from what it would be if there were no CO2 in the atmosphere.
parados wrote:
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If rain takes so much CO2 out of the atmosphere then as we have increased the amount of CO2 in the atmosphere would there not be more taken out in present rains?
Yes! And even more in subsequent rains.
Wouldn't this mean that we would NOT have an increase in atmospheric CO2?
No! It would mean we would have less CO2 in the atmosphere than we otherwise would if it didn't rain.
The big question to be answered is: How is the amount of CO2 in the atmosphere being measured? If it is being measured by direct CO2 measurements aloft, then we have problem #1. If it is being measured by direct measurement of the CO2 in surface polar ice, then we have problem #2.
PROBLEM#1
The direct measurements of CO2 aloft in the atmosphere have been taken since when? 100 years ago? 70 years ago? 50 years ago? 20 years ago? Although I bet it was since less than 70 years ago, let's say it was since 100 years ago. How were the measurements of CO2 taken for the years prior to 100 years ago? I understand those measurements taken for the years prior to 100 years ago, were not taken aloft in the atmosphere, but were taken within the last 100 years from the surface down to various levels (alleged to be equivalent to various ages) of polar ice--the deeper the level, the older the ice. Consequently the older measurements were made of the CO2 that had precipitated in mixtures with H2O and were not actual measurements of CO2 aloft in the atmosphere.
PROBLEM#2
Because past precipitations did not remove all the CO2 in the atmosphere, the CO2 in the polar ice levels at various times in the past cannot be the same as would direct measurements of CO2 aloft in the atmosphere at those same times in the past. So if we are seeking to measure actual CO2 increases in the atmosphere over a great many millennia, we must establish a correlation between the density of CO2 in polar ice at various times and the density of CO2 in the atmosphere at those same times. I'm currently unaware of any such correlation having been scientifically established. Thus, until such correlation is scientifically established, we are in no position to say what is the actual trend of CO2 density in the atmosphere. For all we know more or less CO2 is being washed out of the atmosphere now by higher or lower amounts of precipitation of H2O-CO2-mixture than was true previously due to, respectively, increases or decreases in H2O-CO2-mixtures in the atmosphere.
CONCLUSION
We do not really know whether there has been discovered a scientific cause-and-effect correlation between the amount of CO2 in the atmosphere over the last 100 years and the alleged global warming over the same time period.
In fact the increases or decreases in global temperature may have far more to do with amount of H2O evaporated into the atmosphere from surface water because of variations in the intensity of the sun's radiation than they have to do with the amount of CO2 in the atmosphere.
Also, we know that the amount of heat absorbtion by the CO2-H2O-mixture in the atmosphere is smaller than if there were no CO2 in the atmospheric H2O.
Consequently, the CO2 does not enhance the net heat absorbtion by the atmosphere. It reduces it from what it would be if there were no CO2 in the atmosphere.
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I have been following this argument, but not really knowing where it was going, but ican, what are your qualifications in terms of professional background to make these assertions? And given the conclusion you present, what exactly is the cause of CO2 rising, and when will it plateau out and begin to trend the other way?