@Seed,
Okay, two others were brave enough to answer. It's definately possible to damage the finish.
I often get pine sap on the car, and I start with a craft stick, which I sometimes call popcicle sticks. Remove as much as you can without actually touching the paint. I've never tried Goo Gone, or whatever it's called, and the solvents I use for the final finish work are slow working. Remove as much as possible before starting with the solvent.
I've tried 409 and Windex. Both have worked for me without hurting the finish. They are slow, but with lots of gentle rubbing without letting the solvent evaporate, you will get there. I've also used lighter fluid and the prep solvents intended for final cleaning before painting the car. Both work, but slowly. Neither has damaged
my paint. Your mileage may vary.
Never, never, ever use a carburator cleaner like Barryman B-12. It's an absolutely great solvent, but can destroy paint, rubber, plastic, and your lungs.
Whatever you go with, try it in a very small and out of the way spot.