@georgeob1,
Back in the day, I worked on numerous opposed cylinder configurations, so far as I know, all from Continental and Lycoming. They worked with a sort of three dimensional jigsaw puzzle called cylinder baffling that separated the upper, high pressure section from the lower pressure lower section. Every bit of air coming through the cowling passed around each cylinder. Never saw one coated or painted, except for an orange band indicating they were acceptable for chrom piston rings.
I'm pretty sure the absence of coatings had more to do with inspection than cooling. I'm also pretty well convinced the blackout paint on the hoods of some performance cars was primarily for show. Still, some highways coming out of the Mojave have signs suggesting you turn off you air conditioner in the summer. Anyhow, color of coatings are more taste than function.
George, you mean they still make radial engines? Never did figure out the cam rings on those darn things.