I think the question was very clear, amongst Mexico, Canada and United States, of course United States it is the the more polluter country, but also is the world's biggest polluter, the ozone layer, th weather and earth do not know about economy, about Mexico it is in 3rd world as you said or Canada population and econony can not be compare with US.
The USA is the world's biggest polluter
The worlds largest polluter, America has recently not backed pollution treaties to reduce car emissions or petrol consumption. The US alone accounted for 36.1% of worldwide greenhouse emissions in 1990 [BBC].
"The US contains 4% of the world's population but produces about 25% of all carbon dioxide emissions. By comparison, Britain emits 3% - about the same as India which has 15 times as many people"
BBC: The US and climate change
Many environmentalists understand that developing countries do not have the technology or means to use the most modern or environmentally friendly industrial equipment. But when such a rich country as the USA fails to take responsibility for its own pollution it really annoys a lot of people worldwide. I have created this essay just to concentrate on the USA and President Bush's effect on the Kyoto Protocol because I receive so many emails from people expressing a hatred of the USA because of these issues.
Carbon Dioxide Emissions of the three biggest polluters: (BBC Display of this information)
The USA EU China Total
Population of world: 4.6% 6.3% 21% 31.9%
World economy: 30% 23% 3.2% 56.2%
CO2 Emissions: 24% 14% 13% 51%
China and the EU, both lesser polluters than the US, have one thing in common: They are both committed to further reducing their rate of emissions. Despite economic growth China has cut emissions by 17% since the mid 1990s. The odd one out is the USA. Immensely richer than China, but with less population than Europe, it emits more harmful chemicals than both of them. In addition, it has so far stubbornly refused to endorse international protocols designed to reduce such emissions. The world looks on flabbergasted as the world's greatest polluter cares not to take care or responsibility in the face of international pressure.
Source:
http://www.vexen.co.uk/USA/pollution.html#Pollution