@maxdancona,
Im ageologist whose chemistry background has allowed me to be heavily involved with radiometric dating.
First, we express geological time by events called "Chronozones" where a geological or evolutionry event defines the time period involved, which is a "chron". The chronozones are broken down into ytems , series, and stages of events . The specimens that we date by geo chem and geophysical techniques are used to place a more quantitative time boundary on the specimen. and we see what chron they belong to.
Since concepts like "years" were quite variable through geologic time, all rad dating uses "seconds of decay" as the basis. Then we establish the "years involved" by assigning as if they were in todays duration of a years worth of seconds. Theres a unique decay constnt for every isotope (radioactive). This is being refreshed and calculated finer and finer as our ability to deal with activity levels in the 10"s of millions of AVERAGE decays per second .(Its like differential equations)
So we masure and record the number of decays per second and compute the time based on the ecay constant and "hlf life" of each isotope.
So we compute the age in seconds and convert that to our yers, and this is based on where a fossil or qash or zircon fits within a chronozone. This we age date the chronozone.
Now we also cross check by numerous means using thermal, gravity, mss denisty, hyaline alpha tracking(Used on volcanic glasses like obsidian)," Cosmo" exposure;optical stimulated luminescence, Flourine ion dqting,electron spin resonance, (As well as a whole bunch of other high sounding tricks. We also use old fashioned stratigrphy qnd bio tricks.
The error involved, (depending on the care and QA used in the sample prpep, collwction and analyses) is usually less thn 1% of the count data. This results ina typcally really small error in time (from which you see the "Honest to Joe swing "guess" ) . I usually use a 0.001% tot error if my lab records multiple overlap by running at last 5 duplicates and several field and method blanks.
As Ed said,
1.Creationists have been trying to collect and send in fraud samples to make it seem that old samples are incorrectly datd as young---Like the dinosaur C14/C13 dating which in each case the samples had been doctored by watered down shellac(something like a quarter pound cut, which the lab can be fooled in its washing and cleanup sequences>
2. And to make"young samples" (like ash from a 2 year old volcano) report out as OLD.
Sometimes using a technique erroneously lads to errors and when we know of it we find out that its usually a "Creation SCienc" posse thats trying to be clever. In ALL cases so far, science has ferreted out the fraud and made the Creation"Scientists" look kinda dumb
I knew of a sample of young volcanic ash and zircon that used several methods that had a "young age limit" which meant that, say for K40/Ar39-A40, we dont use this method for anything younger than , say 100 K years.
I was once asked how would I scientifically age date a volcano that erupted two years ago. My answer was that Id go find a newspaper that reported the eruption and see what date was on it.
The creationists try to get away with stupid science qnd then they want kids(and us) to believe theyve got some Biblical based "truth" in their pockets.