@raghav674,
a) 19*100/250 = 7.6 (see chi table) = P(s^2<100) = (1 - p = 1 - .99) = .01
b) 19*500/250 = 38 (see chi table) = P(s^2>500) = (1 - p = 1 - .995) = .005
to answer the other guy about normal distribution:
"The chi-square distribution and the resulting computed probabilities for various values of s^2 require that the population distribution be normal."
Statistics - Newbold, 7th edition, pg. 272