@DrewDad,
To explain my methodology:
There are 216 possible combinations.
1 1 1
1 1 2
1 1 3
etc. through
6 6 4
6 6 5
6 6 6
There are 36 combinations for each beginning number (1 1 1 through 1 6 6).
So:
35 combinations starting with "1" that match the criteria. 35 combinations starting with "5" that match the criteria. 20 combinations for each of the other starting numbers (2,3,4,6)
For total odds of 150/216. Which doesn't match my original probability, because I originally made a fatal flaw in my math.