@MontereyJack,
Carbon dioxide exists in the Earth's atmosphere as a trace gas at a concentration of about 0.04 percent (400 ppm) by volume and has a density about 1.67 times that of air.
Dalton's law of partial pressures: For a mixture of gases in any container, the total pressure exerted is the sum of the pressures that each gas would exert if it were alone.
This law can be expressed in equation form as: p = p1 + p2 + p3 + ...
where p is the total or measured pressure and p1, p2, ... are the partial pressures of the individual gases. For air, an appropriate form of Dalton's law would be: p(air) = p(N2) + p(O2) + p(CO2) + ...
When the total pressure of air is 100 kPa or one bar, the partial pressures of each of its components (in kPa) are numerically equal to the mole per cent of that component (Table). Thus the partial pressures of the major components of dry air at 1 atmosphere (sea level, also as 100 kPa) are : nitrogen, 78 kPa; oxygen, 21 kPa; argon, 0.9 kPa; and carbon dioxide, 0.03 kPa.
Component Mole Per Cent Molar Mass
N2 78.084 28.013
O2 20.948 31.998
Ar 0.934 29.948
CO2 0.0314 44.010
Ne 0.001818 20.183
He 0.000524 4.003
CH4 0.002 16.043
Kr 0.000114 83.80
H2 0.00005 2.016
N2O 0.00005 44.013
Xe 0.0000087 131.30
mass of atmosphere: 5.1 x 10^18 kg
mass of hydrosphere: 1400 x 10^18 kg
The oceans absorb roughly twice as much CO2 as there is in the atmosphere .
1/12 of CO2 increase is man made . The total increase in CO2 is 0.00000211 % per annum . This means 0.00000017583 increase in CO2 as a percentage of the atmosphere is due to man .
Henry's law states: "At a constant temperature, the amount of a given gas that dissolves in a given type and volume of liquid is directly proportional to the partial pressure of that gas in equilibrium with that liquid."
Henry's law can be put into mathematical terms (at constant temperature) as p = k(h) c
where p is the partial pressure of the gaseous solute above the solution, c is the concentration of the dissolved gas and kH is a constant with the dimensions of pressure divided by concentration. The constant, known as the Henry's law constant, depends on the solute, the solvent and the temperature. For a dilute solution, the concentration of the solute is approximately proportional to its mole fraction x . Rewriting Henry's Law, we have c = p/k(h) .
The Henry's Law constant at 15 deg C is 1220, giving a pressure of 2.92 atm or 28 psig assuming salt water is the same as pure water . Solubility goes down as salinity goes up .
Now here's the clincher...I have been unable to find Henry's constant for 15 degree C sea water with 80% humidity air . If you can tell me where you got your constant from ....and you must have one as you say you have already worked this out....I would appreciate it .