@risav11,
P(1) (no spin) = # of ways to roll on loaded chambers = 2
over total # of (remaining) chambers = 5
The probability (P) that you will be shot is at 2/5.
P(2) (spin) = # of ways to roll on a loaded chamber = 2
total # of chambers = 6
The probability (P) that you will be shot is at 1/3.
So rationally, I suggest you should choose not to spin the chamber since the probability that you'll get shot is lesser than spinning it again.