Setanta, you don't want a smooth brain. The more folds, the more surface area and hence intelligence is enhanced (we learned that in H. S. Bio. See:
http://faculty.washington.edu/chudler/brainsize.html for a quick explanation). It also helps if the cerebrum is more developed, as this controls higher functions, whereas the cerebellum handles motor control.
Intelligence is more than physical smarts, which are going to come from heredity, gestation (better prenatal care generally means smarter children, or at least poor prenatal care can result in brain damage, like fetal alcohol syndrome) and environment (e. g. ingestion of lead leads to brain damage).
Intelligence is also education; that is, the smartest person in the world is not so "smart" if they aren't given challenges. This goes along with Phoenix's idea of motivation. It's one thing to be extremely good at arithmetic, versus being extremely bad at advanced calculus. Who's smarter? I posit that the one who's bad at calc is smarter, because it's more of an achievement to work at calc - even if you barely understand it - than it is to rotely spit back the answers to addition problems.
Can you develop intelligence? I'd say yes, to a certain extent. You can't physically improve your brain, or at least we can't at this stage of medical history. However, you can challenge yourself. Do things that are intellectually difficult. This means things like puzzles, riddles and logic problems. You will eventually work out how to do them, if you keep at them long enough. Read more difficult books. It need not be theoretical physics, but reading Proust is harder than reading Stephen King. This is another way to challenge yourself. Another way is to take classes or at least do the readings for advanced classes. Try to learn a foreign language. Tackle programming. Develop artistic, musical or design creativity. Read Philosophy or scientific treatises. I'm not saying that it can all be absorbed, and (much like with physical challenges) you should start small and work your way up. But I think most people can, if they work hard enough and they try hard enough, get at least a fundamental understanding of what may seem at first blush to be rather difficult material.
Oh and another thing - with intelligence, it's often use it or lose it. Education, sadly, ends at age 18 or 21 or 25 for many people. Why not continue it? It doesn't have to be something wholly unpleasant in order to be intellectually stimulating. If foreign languages don't interest you, learn about art. If that doesn't interest you, read advanced material about science. There are thousands of areas of study out there. The pity isn't in trying and failing; the pity is in failing to pursue any of them.