@mihanni21 ,
First define the weekend--is Friday the weekend or not?
If the week is Monday to Thursday (I would) then find the average and the standard deviation for the weekday and the weekend.
Example (from your data)
M-Th ave =21 SD=1
F/S/Su ave=32 SD= sqrt(14/3)
Set the null hypothesis that they are the same, the alternate is they're different. use the averages and SD to determine if the null hypothesis is true or false.
Rap