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Hydrogen electrode

 
 
Reply Sat 7 Oct, 2006 06:24 am
Hi, my question is about the standard hydrogen electrode, it's eqaual to

zero, why?

Thanks for any idea.
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Type: Discussion • Score: 1 • Views: 718 • Replies: 8
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Phoenix32890
 
  1  
Reply Sat 7 Oct, 2006 06:27 am
I don't have the foggiest idea about what this means, Sad but you might find this helpful:

http://en.wikipedia.org/wiki/Standard_hydrogen_electrode
0 Replies
 
Phoenix32890
 
  1  
Reply Sat 7 Oct, 2006 06:33 am
Quote:
standard hydrogen electrode: assigned an electrode potential of exactly zero. The potential of all other electrodes is reported relative to the standard hydrogen electrode.


http://www.chem.purdue.edu/gchelp/gloss/she.html

OK, I am catching on to this. Very Happy
0 Replies
 
navigator
 
  1  
Reply Sun 8 Oct, 2006 11:41 am
Hi Phoenix, thanks for the links. I understand that scientists used it to

measure other materials potential electrodes. They gave it a zero

electrode potential. I still don't get it; why the hydrogen exactly and why

zero?


I think the real potential electrode of hydrogen shouldn't be zero> Maybe

I'm wrong Rolling Eyes
0 Replies
 
talk72000
 
  1  
Reply Sun 8 Oct, 2006 12:29 pm
I guess hydrogen is the confusing factor for you. It is a reference as the electrode is actually composed of an inert metal such as platinum, gold, titanium, etc. It relates to oxidation and reduction processes of aqueous solutions. They are the inverse of each other. Click on
Quote:
redox electrode
on the Wikipedia article.
0 Replies
 
spidergal
 
  1  
Reply Mon 9 Oct, 2006 07:30 pm
Navigator,

The standard hydrogen potential is not zero rather is assigned a potential of zero volts.

Here's why:
The electrode potential (say of oxygen electrode) cannot be determined in isolation, but in a reaction with some other electrode. This is done by measuring the potentials with respect to a standard hydrogen electrode. Tabulating all electrode potentials with respect to the same standard electrode provides a practical working framework for a wide range of calculations and predictions.

It really has nothing to do with the actual potential of hydrogen.
0 Replies
 
talk72000
 
  1  
Reply Mon 9 Oct, 2006 09:28 pm
I think this will give you a better idea of the galvanic series and why hydrogen electrode is zero as it is in the middle of the series:



Galvanic Series
0 Replies
 
navigator
 
  1  
Reply Thu 12 Oct, 2006 11:57 am
Hi everybody n thanks for your reply.

It really makes sense, it isn't basically zero but assigned to be as a

reference to other electrodes. Just like a meter why is it equal to 100 cm,

the same thing.

Thanks spidergal.
0 Replies
 
spidergal
 
  1  
Reply Thu 12 Oct, 2006 12:02 pm
Good you see that now. Very Happy
0 Replies
 
 

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