Yes - I think Molybdenum, the 42nd element is the first element with electrons in the fifth or O shell.
It has 42 Protons, 42 Electrons and 54 Neutrons
http://www.chemicalelements.com/elements/mo.html
Name: Molybdenum
Symbol: Mo
Atomic Number: 42
Atomic Mass: 95.94 amu
Melting Point: 2617.0 °C (2890.15 °K, 4742.6 °F)
Boiling Point: 4612.0 °C (4885.15 °K, 8333.6 °F)
Number of Protons/Electrons: 42
Number of Neutrons: 54
Classification: Transition Metal
Crystal Structure: Cubic
Density @ 293 K: 10.22 g/cm3
Color: silverish
Number of Energy Levels: 5
First Energy Level: 2
Second Energy Level: 8
Third Energy Level: 18
Fourth Energy Level: 13
Fifth Energy Level: 1
http://users.rcn.com/jkimball.ma.ultranet/BiologyPages/E/Elements.html
e.g.