First of all, welcome to A2K. I hope you get a chance to look around. There are lots of good, interesting people here.
You need to first calculate the z-score of a data point. The z-score is calculated easily by the equation:
z = (data_value - mean)/std_deviation
(This puts your data so that the mean is 0, and that "z" is the number of standard deviations from the mean).
Then look the probability up on a table. A fine one is at
http://techniques.geog.ox.ac.uk/mod_2/tables/z-score.htm
The percentile given on this table is the probability any random data point will be less than the given value. For negative z values you can take advantage of the fact that normal distribution is symetrical. This means the new percentile is just p'=1-p
(Unfortunately calculating "area under the normal distribution" is quite difficult. Believe me, the table is the best way to do this.)
For example if your mean is 10 and your standdard deviation is 2 let's caulculate the percentile for the value 13. The z value will be (13-10)/2 or 1.5. From the table 1.5 is .9332, so there will be a 93.32% chance of this value being less than 13.
A data value of 7 would have a negative z-value (i.e. -1.5). We can use 1-.9332 so the percentile would be .0668.
One caveat:
This only works for data that follows a normal distribution. This is true for many types of data, but not all. You need to make sure you understand the data and be confident it follows a normal distribution.
Good luck.