@Brandon9000,
Well, I just asked my friend to explain it to me over a cup of tea with a deck of cards and he did.
Brandon's right (in how he started it) but you'd have to do that for all fifty-two cards multiplying the possibility that it was a snap by the possibility that it wasn't. My friend suggested converting the fractional values to decimals and making a table to compare the values of each probability.
I asked him if he could make a prediction of where the snap would most likely occur - he said he couldn't right off the bat, but that he might do the whole problem and let me know.
He said that this was a very complex, high level problem and that if he'd given this to even the brightest of his a-level maths students - he can't think of one who'd even begin to know how to start it.
He gave me a really good lesson in probabilities - which is the conceptual part of this I was struggling with - even though the order might change, affecting the outcome (which is what I was focusing on) - the probability would stay the same.
Now I get what solipsister was asking.
I'm not gonna work it out though - I'm gonna let Rob do that and when he gives me the answer - I'll post it.