Thanks all. I knew the weatherpersons had to have some way of knowing this in order to report it each day. My searches were not getting me anything for east coast.
Re sunset does not equal darkness... No, but I can start watching over the next few days to get an idea for a "start gathering" time and have some other little activities going until it does get dark enough for the movie to show.
Walter - you were exactly who I expected to have an answer from in the form of a long hand naval formula.