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Organic Chem- Hybridization of NH3- and other stuff

 
 
Reply Wed 12 Sep, 2007 12:51 am
Ok, I dont get the hybridization of (NH3)-, It has 6 valance electrons, with 3 electrons being shared with 3 hydrogen atom. But what about the 3 lone electrons? I know it takes one pair to make a MO. And one more thing, for antibonding and bonding molecular orbital, if their numbers of electrons are the same, that means the compound doesn't exist right?
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helmi15
 
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Reply Wed 12 Sep, 2007 09:25 am
Hi newb!

Nitrogen has 5 valence electrons. Here is a picture of its ground state electron coniguration.

http://genchem.chem.wisc.edu/sstutorial/Text5/Tx54/tx54p3.GIF

As you can see, there are three bondings possible. But this does not explain ammonias properties.

For instance in acid solutions ammonia reacts to NH4+.

NH3 + H+ --> NH4+

It is assumed that at the synthesis of ammonia the 2s and the the three 2p orbitals hybridize. That means they shade off into a higher level of energy. In this case it is called sp3 hybridization - one s oribal, 3 p orbitals.

http://notes.chem.usyd.edu.au/course/masters/Chem1/Special%20Topics/Hybridization/Image376.gif

That's the reason of ammonias structure.
This page shows ammonias structure and similar compounds like methan.
http://www.elmhurst.edu/~chm/vchembook/204tetrahedral.html
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