@rexlincoln,
Of course she's cancelling plans with you in favor of her new guy!
This should come as no great shock to you. The two of you used to do the horizontal tango. I'm sure she realizes her fellow would be hurt by you hanging around with her, particularly alone at your place. What is he supposed to think?
She is, of course, entitled to have and to keep any friends that she chooses. But if she values this new relationship, then she won't do hurtful things if she can help it.
So, what can you do?
Recognize that they now come as a package deal. And maybe they won't forever. But right now, they do. So make plans with
both of them. Give him the option of tagging along, or not.
Otherwise, to him, it just looks like his girlfriend is off to spend time with someone she used to screw, and recently.
How would you feel if you were in his shoes?