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Tue 3 Aug, 2010 10:14 pm
Two electrochemical cells are assembled in which these reactions occur:
V2+ + VO2+ + 2H+ ---------- 2V3+ +H2O E⁰cell = 0.616 V
V3+ + Ag+ + H2O ----------- VO2+ + 2H+ +Ag(s) E⁰cell = 0.439 V
Use these data and other tabulated values of standard half-cell potentials to calculate the standard electrode potential for the half-reaction:
V3+ + e- -------- V2+