Tools - Accounts - Add - Mail
Enter the name you want.
Click Next.
Enter the email address you want to receive mail from.
Click Next.
Enter the POP3 details. It'll be something like : pop.yourISPname.com
Enter the SMTP details. It'll be something like : auth.smtp.yourISPname.com
Click Next.
Enter the account name. This is usually the account's email address ie. the same as the one you entered above.
Enter the account's password.
Click Next.
Click Finish.
Now select the new account in the Accounts window and click on Properties.
Click on the Server tab.
Tick the box that says : My Server Requires Authentication.
Click the Settings button.
Make sure the option to Use The Same Settings As My Incomiong Mail Server is selected.
Click OK.
Click OK.
Click Close.
You're done.