@MiddleMama,
How many things does she do, and what, in particular, is she doing? How long has she been doing this and how does she know him?
I would never organize something for anyone unless asked, and most likely would not do it without the wife being involved.
That's just weird.
I don't think you should question how you feel about it. If you're uncomfortable, you probably have a good reason to feel that way.
No, I don't think you're over-reacting.