Lovatts Crossword & Puzzle Collection 126/Giant Cryptic

I’m stuck on a few. 14 down Phrase upset high-ranking angel (6) ?e?a??
25 across Not so expensive when he gets involved in caper (7) ???a?e?
30 down Duke of Edinburgh and wife flirt? (9) ?h?l?????
73 across In Donegal, van is educationally put into action (10) g?l???????

Any suggestions would be much appreciated. Thanks 😊.