Don't Know if I Should Seek a New Relationship

Hi, first time poster here. So, recently (past month and a half or so) I've been catching up with an old friend from high school. We hadn't really talked or met in five years but we've been talking almost daily since we've started talking again and have met a few times to hang out. And we've been really hitting it off! It's been a lot of fun seeing her again and I've enjoyed talking with her nearly all time. I feel like things could go to relationship status pretty easily.

The only thing is there's quite a lot of complications. First off, she's just got off a serious relationship with her last partner and is actually still in the process of getting a divorce with him. Secondly, while right now she's around three hours from where I live she's planning on moving to Vancouver, which would be at least a days ride for either of us. As much as I enjoy talking to her and spending time with here I'm not sure if right now is an appropriate time to broach the concept of a relationship with her - or even if she's ready for a new relationship.

I really like her and want her to be happy, but I just don't know what's the best, most honest solution to what I'm feeling in this relationship. Any advice? Thanks in advance!