@Oakraider4lif,
I get the feeling he is a friendly guy who really doesn't want to date people he works with, or who doesn't want to do any dating until things are settled with his ex.
Be your usual kind, smiling, professional self with him. I'm sure he would appreciate that. You already put it out there that you think his smile is cute. He'd have to be blind to not realize you mean more than that, but it might just be that the timing is off.