@ehBeth,
I will take a wild guess - you probably want to do this to get back at him...to get him in trouble, to hurt him as he has caused hurt to you.
It is understandable to feel that way - to feel he should be made to suffer, but will it really help you and your wife?
You should focus on your marriage and don't worry about him. If he simply made a mistake then by you just letting it go you are a bigger person; if he is a cheating a$$ - he will get caught and eventually suffer - or anything in between.
You will also don't know his wife - she may not believe you - she could cause trouble for your wife at work; anything bad could happen. I just don't see what good could come of telling a complete stranger news such as this.
Best to move on - let him and any resentment or anger go - and hopefully repair your marriage.