Holiday Giant Cryptic No. 90

TOMORROW
AT LIBERTY
IN EARNEST
IMMEDIATE
ETIQUETTE

Thank you Cherrie, much appreciated, can I ask another favour. another 5.
55d Chess pieces jump to loans office (8)
56d Exhausted and destroyed by fire (5,3)
25a Enigma calls himself Mr E (7)
40a Idiot hung around remaining concealed (6,3)
54d Radiant, you see, in Lent (6)

thank you in advance

55d pawn shop
5d ?
25a mystery
40a ?
54d lucent

BURNT OUT
HIDING OUT

Hi all, and thank you for your help so far, can I impose on you again on some more questions, I have some letters this time - hope they are correct.

8d Presenting a combat bell sound (8)A _ M _ D _ _ _
9d Map owner can change the workforce (8) M _ N _ _ _ _ _
22a Ascent changed point of view (6) _ T _ _ _ _
31d Characters hated part of dangerous structure (5,4) _ R _ T _ T _ G _
52d Blood factor for some doctor, he suspects (6) E _ E _ U _
49d More avid than funeral wailer (6) _ T _ N _ _
57d The French competing with imposing taxes (7) _ E _ _ _ N _
66a Synthetic fabric or any changes (5) _ _ _ _ N

Once again thank you all in advance.

Presenting a combat bell sound: awarding
9d Map owner can change the workforce: manpower
22a Ascent changed point of view: stance
31d Characters hated part of dangerous structure: death trap
52d Blood factor for some doctor, he suspects: Rhesus
49d More avid than funeral wailer: keener
57d The French competing with imposing taxes: fencing
66a Synthetic fabric or any changes: nylon

Maybe...

57d LEVYING
66a RAYON

Timur is right with all the others.