@jespah,
Thanks jespah, clues are as follows:
20 across; black magic, sounds like a religious offshoot; o?c?l?
45 across; pops on net disturbing adversaries; ?p???e?t?
5 down; frost-free from a ghost in Tyrone's county town, nth ireland; o?a?h
37 down; drought-resistant herb allegedly carried by achilles to staunch bleeding wounds; y?r???
I hope this is of help, thanks