@adippered,
Hi adippered,
I don't have all the answers but here's a few that I do have:
14d - unhoped for
36d - figurehead
76d - mercurial
157d - churned
74a - calumnies
112a - balalaika
162 - gloop
I'm sorry but I'm stuck on the other ones as well!
Anyway, hopefully someone will confirm my answers above and help with the others!
Good luck!
Sophc